PEO-PPO-PEO triblock copolymer in aqueous solution. Micelle formation and crystallization
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چکیده
منابع مشابه
PEO-PPO-PEO triblock copolymer in aqueous solution. Micelle formation and crystallization
The phase behavior of poly(ethy1ene oxide) poly(propy1ene oxide) poly(ethy1ene oxide), PEO-PPO-PEO, tri-block copolymers dissolved in water has been studied using small-angle neutron scattering, using a Couette device for shear alignments. The structural properties has been studied as a function of polymer concentration and temperature. At low-temperature and low polymer concentrations the unim...
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The solubilization of hydrocarbons by micelles formed of diblock and symmetric triblock copolymers in water are compared in the framework of a mean-field theory of solubilization. The block copolymers contain poly(ethylene oxide) as the hydrophilic block and poly(propylene oxide) as the hydrophobic block and are designated as EXPYEX or EWPZ (where E and P denote ethylene and propylene oxides an...
متن کاملBoundary Lubrication of PEO-PPO-PEO Triblock Copolymer Physisorbed on Polypropylene, Polyethylene, and Cellulose Surfaces
In situ lateral force microscopy (LFM) and X-ray photoelectron spectroscopy (XPS) were used to probe the lubrication behavior of an aqueous solution of poly(oxyethylene)-poly(oxypropylene)-poly(oxyethylene) (PEO-PPO-PEO) symmetric triblock copolymer on thin films of polypropylene (PP), polyethylene (PE), and cellulose. LFM experiments were carried out while the substrates were immersed in water...
متن کاملAdsorption and association of a symmetric PEO-PPO-PEO triblock copolymer on polypropylene, polyethylene, and cellulose surfaces.
The association of a symmetric polyoxyethylene-polyoxypropylene-polyoxyethylene (PEO(19)-PPO(29)-PEO(19)) triblock copolymer adsorbed from aqueous solutions onto polypropylene (PP), polyethylene (PE), and cellulose surfaces was probed using Atomic Force Microscopy (AFM). Significant morphological differences between the polyolefin substrates (PP and PE) and the cellulose surfaces were observed ...
متن کاملPreparation of echinoid-like aggregated hematite particles by forced hydrolysis with PEO-PPO-PEO triblock copolymers
Sub-micrometre sized hematite particles with a controlled structure were prepared by forced hydrolysis of a Fe(NO3)3·9H2O aqueous solution in the presence of poly(alkylene oxide) triblock copolymer (Pluronic P123). The resulting particles show an echinoid-like shape and a narrow size distribution. After removal of the polymer by calcination at 500 C for 3 h, the resulting particles show a retai...
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ژورنال
عنوان ژورنال: Le Journal de Physique IV
سال: 1993
ISSN: 1155-4339
DOI: 10.1051/jp4:1993830